A group consisting of Professor Kazushi Mashima of Osaka University and Kazuhiko Sato, Director of the Research Center for Catalytic Chemistry, National Institute of Advanced Industrial Science and Technology, has succeeded in producing a high-performance catalyst from inexpensive nickel.It may help reduce the manufacturing cost of medicines made with expensive catalysts.
Iron and nickel are metals that are candidates for cheap catalysts.However, it had the drawback of lower performance as a catalyst than precious metals.Professor Mashima et al. Discovered that nickel particles of about 15 nm (1 nanometer = 0.000000001 m) are formed by reacting a nickel compound with an organic substance containing silicon.Further examination of these particles revealed that they had an atomic arrangement (amorphous) different from that of metal crystals.When these amorphous nickel nanoparticles were used as a catalyst for organic synthesis, they showed extremely high performance. ..This is far superior to catalysts made from precious metals.It is known that nickel atoms released from nanoparticles act as catalysts, but further investigation revealed that amorphous particles have the effect of releasing and re-incorporating atoms, which is a catalyst for catalysts. I also found that it was functioning as a storage.
In the future, we plan to proceed with research to apply this catalyst to various chemical reactions required in actual organic synthesis.If realized, it can be expected that the manufacturing cost of familiar products such as pharmaceuticals can be greatly reduced, and the burden on the environment due to the use of precious metals can be reduced.